1-METHOXY-1,3-CYCLOHEXADIENE , 0.95&0.99 , 2161-90-2

Synonym(s):
2,3-Dihydroanisole

CAS NO.：2161-90-2

Empirical Formula: C7H10O

Molecular Weight: 110.15

MDL number: MFCD00001533

PRODUCT Properties

• Melting point: 96-97 °C
• Boiling point: 40 °C/15 mmHg (lit.)
• Density: 0.929 g/mL at 25 °C (lit.)
• refractive index: n20/D 1.488(lit.)
• Flash point: 80 °F
• LogP: 1.790 (est)

Description and Uses

1-Methoxy-1,3-cyclohexadiene was used in the following studies:

• Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
• Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
• Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.

Safety

• Symbol(GHS): GHS02,GHS07
• Signal word: Warning
• Hazard statements: H226-H302+H312+H332
• Precautionary statements: P210-P233-P280-P301+P312-P303+P361+P353-P304+P340+P312
• Hazard Codes: Xn
• Risk Statements: 10-20/21/22
• Safety Statements: 16-33-36/37/39
• RIDADR: UN 1993 3/PG 3
• WGK Germany: 3
• HazardClass: 3.2
• PackingGroup: III