Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate , 98+% , 35138-22-8

Synonym(s):
Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

CAS NO.：35138-22-8

Empirical Formula: C16H24BF4Rh

Molecular Weight: 406.07

MDL number: MFCD00075045

EINECS: 460-220-1

PRODUCT Properties

• Melting point: 210 °C
• Density: 0.42 g/cm3 (20℃)
• storage temp.: Inert atmosphere,Store in freezer, under -20°C
• solubility: Chloroform (Slightly), Methanol (Slightly)
• form: Powder
• color: Red
• PH: 7 (5g/l, H2O, 20℃)
• Water Solubility: insoluble
• Sensitive: Slightly air & moisture sensitive
• Exposure limits: ACGIH: TWA 1 mg/m3; NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
• InChIKey: IEMMJJILGGBYNZ-GSLAGHMSSA-M

Description and Uses

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

Safety

• Symbol(GHS): GHS02,GHS07
• Signal word: Warning
• Hazard statements: H228-H315-H317-H319-H335
• Precautionary statements: P210-P240-P241-P280-P302+P352-P305+P351+P338
• Hazard Codes: F,Xi
• Risk Statements: 11-34
• Safety Statements: 16-45-36/37/39-26
• RIDADR: UN 2921
• WGK Germany: 2
• Hazard Note: Irritant
• TSCA: No
• HazardClass: 8
• PackingGroup: III
• HS Code: 28439000