A0363156
Dichloro(1,5-cyclooctadiene)palladium(II) , 99.95%metalsbasis
Synonym(s):
PdCl2(cod)
CAS NO.:
Empirical Formula: C8H12Cl2Pd
Molecular Weight: 285.51
MDL number: MFCD00012412
EINECS: 235-161-8
Pack Size | Price | Stock | Quantity |
2g | RMB1439.20 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 210 °C (dec.) (lit.) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Soluble in dichloromethane |
form | crystal |
color | yellow |
Water Solubility | insoluble |
Sensitive | Hygroscopic |
InChI | InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; |
InChIKey | NEKYMUKEOUDFPP-XRGHXPOKSA-L |
SMILES | C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6| |
Description and Uses
Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.
Safety
Symbol(GHS) | GHS07 |
Signal word | Warning |
Hazard statements | H315-H319-H335 |
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-37/39 |
WGK Germany | 3 |
TSCA | Yes |
HS Code | 28439000 |