Home Categories Organic Chemistry Dichloro(1,5-cyclooctadiene)palladium(II)
A0363156

Dichloro(1,5-cyclooctadiene)palladium(II) , 99.95%metalsbasis

Synonym(s):
PdCl2(cod)

CAS NO.:

Empirical Formula: C8H12Cl2Pd

Molecular Weight: 285.51

MDL number: MFCD00012412

EINECS: 235-161-8

Pack Size Price Stock Quantity
2g RMB1439.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 210 °C (dec.) (lit.)
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in dichloromethane
form  crystal
color  yellow
Water Solubility  insoluble
Sensitive  Hygroscopic
InChI InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChIKey NEKYMUKEOUDFPP-XRGHXPOKSA-L
SMILES C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6|

Description and Uses

Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
TSCA  Yes
HS Code  28439000

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