A3172712
Dichloro(1,5-cyclooctadiene)palladium(II) , Pd37.3% , 12107-56-1
Synonym(s):
PdCl2(cod)
CAS NO.：12107-56-1
Empirical Formula: C8H12Cl2Pd
Molecular Weight: 285.51
MDL number: MFCD00012412
EINECS: 235-161-8
| Pack Size | Price | Stock | Quantity |
| 250mg | RMB239.20 | In Stock |
|
| 1G | RMB639.20 | In Stock |
|
| 5G | RMB2239.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 210 °C (dec.) (lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in dichloromethane |
| form | crystal |
| color | yellow |
| Water Solubility | insoluble |
| Sensitive | Hygroscopic |
| InChI | InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; |
| InChIKey | NEKYMUKEOUDFPP-XRGHXPOKSA-L |
| SMILES | C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6| |
| CAS DataBase Reference | 12107-56-1(CAS DataBase Reference) |
| EPA Substance Registry System | Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1) |
Description and Uses
Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| TSCA | Yes |
| HS Code | 28439000 |
