(R)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl , 98% , 139139-86-9

Synonym(s):
(R)-(+)-2,2′-Bis(diphenylphospino)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl;[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro-[1,1′-binaphthalene]-2,2′-diyl]bis[diphenylphosphine]

CAS NO.：139139-86-9

Empirical Formula: C44H40P2

Molecular Weight: 630.74

MDL number: MFCD01630795

PRODUCT Properties

• Melting point: 207-208°C
• Boiling point: 745.6±60.0 °C(Predicted)
• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• form: Powder
• color: off-white
• optical activity: [α]20/D +74°, c = 0.5 in toluene
• CAS DataBase Reference: 139139-86-9

Description and Uses

Catalytic ligand used for:

• Enantioselective synthesis of dihydrobenzofurans and dihydronaphthofurans via olefin isomerization/enantioselective intramolecular Alder-ene reaction of enynes catalyzed by Rh
• Preparation of axially chiral biaryl compounds by gold-catalyzed stereoselective intramolecular hydroarylation
• Preparation of chiral 3-alkyl-substituted indolines by tandem condensation-asymmetric hydrogenation of indoles with aldehydes, catalyzed by Bronsted acids and palladium BINAP complexes
• Stereoselective preparation of hydrindanes and decalins containing up to four contiguous stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of ene-allenes with allenes
• Rhodium-catalyzed asymmetric formal olefination or cycloaddition of 1,3-dicarbonyl compounds with 1,6-diynes or 1,6-enynes
• Stereoselective preparation of 2,3-substituted indolines via Pd-catalyzed hydrogenation of (α-hydroxyalkyl)indoles

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319
• Precautionary statements: P302+P352-P305+P351+P338
• Hazard Codes: Xi
• Risk Statements: 36/38
• Safety Statements: 26
• WGK Germany: 3