Home Categories (S)-5,5'-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole
BD2766545

(S)-5,5'-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole , 98%99%ee , 210169-40-7

Synonym(s):
(S)-(+)-5,5′-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4′-bi-1,3-benzodioxole

CAS NO.:210169-40-7

Empirical Formula: C74H100O8P2

Molecular Weight: 1179.53

MDL number: MFCD09753003

Pack Size Price Stock Quantity
100mg RMB59.20 In Stock
250mg RMB112.00 In Stock
1g RMB381.60 In Stock
5g RMB1568.80 In Stock
25g RMB6326.40 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 126-128°C
Boiling point: 987.3±65.0 °C(Predicted)
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  Powder
color  off-white
CAS DataBase Reference 210169-40-7

Description and Uses

Catalytic ligand for:

  • Enantioselective synthesis of secondary allylic alcohols via enantioselective reductions of α,β-unsaturated ketones
  • Stereoselective preparation of cyclohexanone derivatives via rhodium-catalyzed rearrangement of allyl or allenic cyclobutanols
  • Cu-catalyzed asymmetric conjugate reduction of beta-substituted unsaturated phosphonates to give optically active beta-stereogenic alkylphosphonates
  • Asymmetric synthesis of cyclohexenones via Rh-catalyzed desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
  • Enantioselective synthesis and crystal structure of P-stereogenic alkynylphosphine oxides by Rh-catalyzed [2+2+2] cycloaddition

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
WGK Germany  3
HS Code  2932.99.7000

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