Home Categories Chemical Reagents Potassium bis(trimethylsilyl)amide
A6862712

Potassium bis(trimethylsilyl)amide , 0.5M(11wt.%)toluenesolution , 40949-94-8

Synonym(s):
Hexamethyldisilazane potassium salt;Hexamethyldisilazane potassium salt solution;KHMDS;Potassium hexamethyldisilazide;Potassium hexamethyldisilazide solution

CAS NO.:40949-94-8

Empirical Formula: C6H18KNSi2

Molecular Weight: 199.48

MDL number: MFCD00010330

EINECS: 424-100-2

Pack Size Price Stock Quantity
100ML RMB239.20 In Stock
500ML RMB799.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 194-195°C
Boiling point: 111 °C
Density  0.877 g/mL at 25 °C
vapor density  3.2 (vs air)
vapor pressure  54 mm Hg ( 25 °C)
refractive index  1.4920
Flash point: 45 °F
storage temp.  Refrigerator
solubility  Miscible with terahydrofuran, ether, benzene and toluene.
form  Liquid
Specific Gravity 0.877
color  clear to slightly hazy yellow
Water Solubility  Reacts with water.
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
BRN  4006754

Description and Uses

Potassium Hexamethyldisilazide is widely used as a Sterically Hindered Base for Enolate Generation in Selective Formation of Linear Conjugated Dienolates and Alkyl (Z)-3-Alkenoates.

Safety

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,F,Xn
Risk Statements  14-34-67-65-63-48/20-11-40-36/37/38-19-37
Safety Statements  26-36/37/39-45-62-43-46-16-36/37
RIDADR  UN 3263 8/PG 3
WGK Germany  3
1-3-10
TSCA  No
HazardClass  3
PackingGroup  II
HS Code  29319090

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