Home Categories Chemical Reagents Potassium bis(trimethylsilyl)amide
A6687912

Potassium bis(trimethylsilyl)amide , 1MINTHF (about 22%content) , 40949-94-8

Synonym(s):
Hexamethyldisilazane potassium salt;Hexamethyldisilazane potassium salt solution;KHMDS;Potassium hexamethyldisilazide;Potassium hexamethyldisilazide solution

CAS NO.:40949-94-8

Empirical Formula: C6H18KNSi2

Molecular Weight: 199.48

MDL number: MFCD00010330

EINECS: 424-100-2

Pack Size Price Stock Quantity
100ML RMB102.40 In Stock
500ML RMB568.80 In Stock
1L RMB1012.80 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 194-195°C
Boiling point: 111 °C
Density  0.877 g/mL at 25 °C
vapor density  3.2 (vs air)
vapor pressure  54 mm Hg ( 25 °C)
refractive index  1.4920
Flash point: 45 °F
storage temp.  Refrigerator
solubility  Miscible with terahydrofuran, ether, benzene and toluene.
form  Liquid
Specific Gravity 0.877
color  clear to slightly hazy yellow
Water Solubility  Reacts with water.
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Sensitive  Moisture Sensitive
BRN  4006754
CAS DataBase Reference 40949-94-8(CAS DataBase Reference)
EPA Substance Registry System Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, potassium salt (1:1) (40949-94-8)

Description and Uses

Potassium Hexamethyldisilazide is widely used as a Sterically Hindered Base for Enolate Generation in Selective Formation of Linear Conjugated Dienolates and Alkyl (Z)-3-Alkenoates.

Safety

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,F,Xn
Risk Statements  14-34-67-65-63-48/20-11-40-36/37/38-19-37
Safety Statements  26-36/37/39-45-62-43-46-16-36/37
RIDADR  UN 3263 8/PG 3
WGK Germany  3
1-3-10
TSCA  No
HazardClass  3
PackingGroup  II
HS Code  29319090

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