Home Categories Organic Chemistry 4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline
A4687512

4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline , 97% , 69563-88-8

Synonym(s):
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane;4′,4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline)

CAS NO.:69563-88-8

Empirical Formula: C27H20F6N2O2

Molecular Weight: 518.45

MDL number: MFCD00015723

EINECS: 626-703-8

Pack Size Price Stock Quantity
5G RMB60.80 In Stock
25G RMB209.60 In Stock
100G RMB616.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 159-163 °C(lit.)
Boiling point: 544.8±50.0 °C(Predicted)
Density  1.3455 (estimate)
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
Water Solubility  Insoluble in water
solubility  Soluble in DMSO
form  powder to crystal
pka 4.80±0.10(Predicted)
color  White to Almost white
InChIKey HHLMWQDRYZAENA-UHFFFAOYSA-N

Description and Uses

2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications[1].

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  CY1213000
HazardClass  IRRITANT
HS Code  29222990

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