4,4′-(Hexafluoroisopropylidene)bis(p-phenyleneoxy)dianiline , 97% , 69563-88-8
Synonym(s):
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane;4′,4′′′-(Hexafluoroisopropylidene)bis(4-phenoxyaniline)
CAS NO.：69563-88-8
Empirical Formula: C27H20F6N2O2
Molecular Weight: 518.45
MDL number: MFCD00015723
EINECS: 626-703-8
| Pack Size | Price | Stock | Quantity |
| 5G | RMB60.80 | In Stock |
|
| 25G | RMB209.60 | In Stock |
|
| 100G | RMB616.00 | In Stock |
|
| others | Enquire |
PRODUCT Properties
| Melting point: | 159-163 °C(lit.) |
| Boiling point: | 544.8±50.0 °C(Predicted) |
| Density | 1.3455 (estimate) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| Water Solubility | Insoluble in water |
| solubility | Soluble in DMSO |
| form | powder to crystal |
| pka | 4.80±0.10(Predicted) |
| color | White to Almost white |
| InChIKey | HHLMWQDRYZAENA-UHFFFAOYSA-N |
| CAS DataBase Reference | 69563-88-8(CAS DataBase Reference) |
| EPA Substance Registry System | Benzenamine, 4,4'-[[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis(4,1-phenyleneoxy)]bis- (69563-88-8) |
Description and Uses
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) is composed of two phenoxyanilines linked by a hexafluoroisopropane. 4-BDAF is commonly used in the synthesis of polyimides, and the semicrystalline and amorphous fluorinated polyimides developed have high transition temperatures and good The developed semi-crystalline and amorphous fluorinated polyimides have high transition temperatures and good thermal stability. Polyimides derived from 4-BDAF and trimellitic anhydride (PMDA) are semi-crystalline and have a melting point of 472°C. Addition of 6F dianhydride (2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 6FDA) as a copolymer monomer to the PMDA/4-BDAF polyimides lowers the melting point to 440°C. The melting point of the polyimides is reduced to 440°C by using 1,1-bis(4-aminophenyl)-1 Polyimides based on 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F diamine, 3FDAM) are soluble and amorphous. The glass transition temperature of PMDA/3FDAM-based polyimides exceeds 420°C. These fluoropolyimide systems are currently being investigated as candidates for high-temperature applications[1].
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]HEXAFLUOROPROPANE is used for the preparation of a polyimide material.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 |
| Hazard Codes | Xn,Xi |
| Risk Statements | 22-36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
| RTECS | CY1213000 |
| HazardClass | IRRITANT |
| HS Code | 29222990 |
