Home Categories Chemical Reagents 4,4′-(9-Fluorenylidene)dianiline
A4339512

4,4′-(9-Fluorenylidene)dianiline , 99% , 15499-84-0

CAS NO.:15499-84-0

Empirical Formula: C25H20N2

Molecular Weight: 348.44

MDL number: MFCD00039156

EINECS: 628-740-5

Pack Size Price Stock Quantity
1g RMB20.00 In Stock
5G RMB23.20 In Stock
25G RMB55.20 In Stock
100G RMB159.20 In Stock
500g RMB687.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 237-239 °C (lit.)
Boiling point: 535.2±50.0 °C(Predicted)
Density  1.245±0.06 g/cm3(Predicted)
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
Water Solubility  Insoluble in water
form  powder to crystal
pka 4.92±0.10(Predicted)
color  White to Almost white
InChI InChI=1S/C25H20N2/c26-19-13-9-17(10-14-19)25(18-11-15-20(27)16-12-18)23-7-3-1-5-21(23)22-6-2-4-8-24(22)25/h1-16H,26-27H2
InChIKey KIFDSGGWDIVQGN-UHFFFAOYSA-N
SMILES C1(C2=CC=C(N)C=C2)(C2=CC=C(N)C=C2)C2=C(C=CC=C2)C2=C1C=CC=C2

Description and Uses

9,9-Bis(4-aminophenyl)fluorene (FDA) is a fluorene derivative with two aminophenyl substituents on the 9-position. This compound has partial conjugation and can be utilized as a dopant-free organic hole-transporting material in inverted perovskite solar cells. Due to its diaminophenyl groups, FDA is commonly employed in synthesizing polyimides that possess high thermal and hydrolytic stability for optical fiber light guide coatings. Because the FDA is not fully aromatized, it is chosen to produce thermally stable transparent polyimides. Additionally, the polyimide derived from 9,9-bis(4-aminophenyl)fluorene can be further modified through Friedel-Crafts alkylation on the fluorene moiety, as the polyimide backbone remains chemically stable.

9,9-bis(4-aminophenyl)fluorene be used for preparation of high-strength material and high-temperature polymers.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37
Safety Statements  26-36
WGK Germany  3
HazardClass  IRRITANT
HS Code  29215900

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