Home Categories Organic Chemistry Ethylene glycol butyl ether
A3970112

Ethylene glycol butyl ether , AR,99.0% , 111-76-2

Synonym(s):
2-Butoxyethanol;Butyl glycol;Ethylene glycol butyl ether;Ethylene glycol monobutyl ether;Ethylene Glycol Monobutyl Ether, Butoxyethanol

CAS NO.:111-76-2

Empirical Formula: C6H14O2

Molecular Weight: 118.17

MDL number: MFCD00002884

EINECS: 203-905-0

Update time: 2022-07-08

PRODUCT Properties

Melting point: -70 °C
Boiling point: 171 °C
Density  0.902 g/mL at 25 °C(lit.)
vapor density  4.1 (vs air)
vapor pressure  <1 mm Hg ( 20 °C)
refractive index  n20/D 1.419(lit.)
Flash point: 140 °F
storage temp.  Store below +30°C.
solubility  900g/l completely miscible
form  Liquid
pka 14.42±0.10(Predicted)
color  Clear
PH 7 (H2O, 20℃)(as aqueous solution)
Odor Mild, characteristic; slightly rancid; mild ethereal.
Odor Threshold 0.043ppm
explosive limit 1.1-10.6%(V)
Water Solubility  miscible
λmax λ: 230 nm Amax: 1.0
λ: 250 nm Amax: 0.10
λ: 275 nm Amax: 0.05
λ: 300-400 nm Amax: 0.01
Merck  14,1559
BRN  1732511
Henry's Law Constant (x 10-6 atm?m3/mol): 2.36 (approximate - calculated from water solubility and vapor pressure)
Exposure limits TLV-TWA skin 25 ppm (121 mg/m3) (ACGIH), 50 ppm (242 mg/m3) (OSHA); STEL 75 ppm (363 mg/m3) (ACGIH);IDLH 700 ppm (NIOSH). .
Dielectric constant 5.2999999999999998
LogP 0.81 at 20℃

Description and Uses

2-Butoxyethanol is a clear, colourless liquid with ether-like smell.2-Butoxyethanol is usually produced by a reaction of ethylene oxide with butyl alcohol, but it may also be made by the reaction of ethylene glycol with dibutyl sulphate. 2-Butoxyethanol is widely used as a solvent in protective surface coatings such as spray lacquers, quick-dry lacquers, enamels, varnishes, and latex paints. It is also used as an ingredient in paint thinners and strippers, varnish removers, agricultural chemicals, herbicides, silicon caulks, cutting oils, and hydraulic fluids and as metal cleaners, fabric dyes and inks, industrial and household cleaners (as a degreaser), and dry-cleaning compounds. It is also used in liquid soaps and in cosmetics. 2-Butoxyethanol acetate has been reported to be present in air, water, and soil as a contaminant and exposure to it occurs during its manufacture and use as an intermediate in the chemical industry, and during the formulation and use of its products in multiple industrial activities. The acetate form of 2-butoxyethanol is 2-butoxyethanol acetate and also known as ethylene glycol monobutyl ether acetate.

Ethylene glycol monobutyl ether (EGBE) is used as a solvent for nitrocellulose, resins, oil, and grease, and in dry cleaning.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H332-H315-H319
Precautionary statements  P261-P264-P301+P312-P302+P352-P304+P340+P312-P305+P351+P338
Hazard Codes  Xn
Risk Statements  20/21/22-36/38
Safety Statements  36/37-46
RIDADR  1986
OEB A
OEL TWA: 5 ppm (24 mg/m3) [skin]
WGK Germany  1
RTECS  KJ8575000
Autoignition Temperature 473 °F
TSCA  Yes
HS Code  2909 43 00
HazardClass  6.1
PackingGroup  III
Toxicity LD50 orally in rats: 1.48 g/kg (Smyth)
IDLA 700 ppm

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