Home Categories (R)-3,3'-Dibromo-1,1'-bi-2-naphthol
A3267512

(R)-3,3'-Dibromo-1,1'-bi-2-naphthol , 97% , 111795-43-8

CAS NO.:111795-43-8

Empirical Formula: C20H12Br2O2

Molecular Weight: 444.12

MDL number: MFCD03093629

Pack Size Price Stock Quantity
250MG RMB462.40 In Stock
1G RMB1004.80 In Stock
5G RMB3677.60 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 256-260 °C
alpha  +43° (c 0.22, CHCl3)
Boiling point: 469.9±40.0 °C(Predicted)
Density  1.761±0.06 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
solubility  within almost transparency in Methanol
form  Powder
pka 6.43±0.50(Predicted)
color  White to pale yellow-beige

Description and Uses

(R)-(+)-3,3′-Dibromo-1,1′-bi-2-naphthol reacts with zirconium(IV) tert-butoxide to form a chiral zirconium complex, which can efficiently catalyze:

  • anti-selective catalytic asymmetric aldol reactions of silyl enol ethers with aldehydes
  • asymmetric intramolecular [3+2] cycloaddition of hydrazone/olefins

Safety

Symbol(GHS) 
GHS09
Signal word  Warning
Hazard statements  H410
Precautionary statements  P273-P501
Hazard Codes  Xn
Risk Statements  36/37/38-22
Safety Statements  26-36/37/39-37/39
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
HS Code  29081990

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