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A1242012

(R)-(+)-1,1′-Bi(2-naphthol) , 99% , 18531-94-7

Synonym(s):
(+)-2,2′-Dihydroxy-1,1′-dinaphthyl;(R)-(+)-1,1′-Binaphthalene-2,2′-diol;(R)-BINOL

CAS NO.:18531-94-7

Empirical Formula: C20H14O2

Molecular Weight: 286.32

MDL number: MFCD00004068

EINECS: 606-048-4

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5G RMB24.00 In Stock
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100G RMB268.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 215-218 °C
alpha  35.5 º (c=1, THF)
Boiling point: 388.69°C (rough estimate)
Density  1.301
refractive index  36.0 ° (C=1, THF)
storage temp.  Store below +30°C.
solubility  dioxane: 50 mg/mL, clear
form  Powder
pka 8.29±0.50(Predicted)
color  white to off-white
optical activity [α]21/D +34°, c = 1 in THF
Water Solubility  Insoluble in water. Solubility in THF within almost transparency). Soluble in dioxane 50 mg/mL.
Merck  14,1226
BRN  3616837
CAS DataBase Reference 18531-94-7(CAS DataBase Reference)

Description and Uses

Chiral binapthol imminium salt precursor. Salts were used for an asymmetric epoxidation of olefins.

Safety

Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H301-H315-H319
Precautionary statements  P301+P310+P330-P302+P352-P305+P351+P338
Hazard Codes  T,Xi
Risk Statements  25-36-36/37/38
Safety Statements  26-45-24/25-36
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
RTECS  DU3106100
10
TSCA  No
HazardClass  6.1
PackingGroup  III
HS Code  29071590
Toxicity LD50 orally in Rabbit: 113 mg/kg

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