Home Categories Organic Chemistry 1,2-Butylene Oxide
A1531912

1,2-Butylene Oxide , >99.0%(GC) , 106-88-7

Synonym(s):
1,2-Epoxybutane;1-Butene oxide;Ethyloxirane;Ethyloxirane, 1,2-Butylene oxide;α-Butylene oxide

CAS NO.:106-88-7

Empirical Formula: C4H8O

Molecular Weight: 72.11

MDL number: MFCD00005153

EINECS: 203-438-2

Update time: 2022-07-08

PRODUCT Properties

Melting point: -129.28°C
Boiling point: 63 °C(lit.)
Density  0.829 g/mL at 20 °C(lit.)
vapor density  2.2 (vs air)
vapor pressure  140 mm Hg ( 20 °C)
refractive index  n20/D 1.384
Flash point: 10 °F
storage temp.  Store below +30°C.
solubility  86.8g/l
form  Colorless liquid with pungent odor
color  Colorless to Almost colorless
PH 7 (50g/l, H2O, 20℃)
explosive limit 1.7-19%(V)
Water Solubility  86.8g/L at 25℃
BRN  102411
Stability: Stable, but prone to polymerization - stabilizer may be added to neat liquid. Highly flammable. Incompatible with strong oxidizing agents, acids, bases, anhydrous metal halides, amino, hydroxyl and carboxyl-containing compounds. Inorganic acids and charcoal may lead to polymerization. Heat, light and moisture sensitive.
InChIKey RBACIKXCRWGCBB-UHFFFAOYSA-N
LogP 0.68 at 25℃
CAS DataBase Reference 106-88-7(CAS DataBase Reference)
IARC 2B (Vol. 47, 71) 1999
EPA Substance Registry System 1,2-Butylene oxide (106-88-7)

Description and Uses

Butylene oxide is a watery white liquid withan etherial odor. Molecular weight = 72.1 (1,2- and 2,3-isomers);Specific gravity (H2O:1) = 0.83; Boilingpoint = 63.3℃; Freezing/Melting point = - 130℃; Vaporpressure = 142 mmHg at 20℃; 176 mmHg at 25℃;Relative vapor density (air = 1) = 2.2; Relative density ofthe vapor/air mixture at 20C (air = 1) = 1.3; Flashpoint = - 22℃; Autoignition temperature = 439℃.Explosive limits in air: LEL: 1.7%; UEL: 19%. HazardIdentification (based on NFPA-704 M Rating System):Health 2, Flammability 3, Reactivity 2. Soluble in water;solubility = 9.5% at 25℃.

Primarily used as a stabilizer for chlorinated hydrocarbon solvents; also used as a chemical intermediate in the production of butylene glycols

Safety

Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H302+H312+H332-H315-H319-H335-H351
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P308+P313
Hazard Codes  F,Xn
Risk Statements  11-20/21/22-36/37/38-40-52/53
Safety Statements  9-16-29-36/37-61-19
RIDADR  UN 3022 3/PG 2
WGK Germany  2
RTECS  EK3675000
Autoignition Temperature 698 °F
TSCA  Yes
HazardClass  3.1
PackingGroup  II
HS Code  29109000
Hazardous Substances Data 106-88-7(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 500 mg/kg LD50 dermal Rabbit 1743 mg/kg

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