1,2-Butylene Oxide , >99.0%(GC) , 106-88-7
Synonym(s):
1,2-Epoxybutane;1-Butene oxide;Ethyloxirane;Ethyloxirane, 1,2-Butylene oxide;α-Butylene oxide
CAS NO.:106-88-7
Empirical Formula: C4H8O
Molecular Weight: 72.11
MDL number: MFCD00005153
EINECS: 203-438-2
PRODUCT Properties
Melting point: | -129.28°C |
Boiling point: | 63 °C(lit.) |
Density | 0.829 g/mL at 20 °C(lit.) |
vapor density | 2.2 (vs air) |
vapor pressure | 140 mm Hg ( 20 °C) |
refractive index | n |
Flash point: | 10 °F |
storage temp. | Store below +30°C. |
solubility | 86.8g/l |
form | Colorless liquid with
pungent odor |
color | Colorless to Almost colorless |
PH | 7 (50g/l, H2O, 20℃) |
explosive limit | 1.7-19%(V) |
Water Solubility | 86.8g/L at 25℃ |
BRN | 102411 |
Stability: | Stable, but prone to polymerization - stabilizer may be added to neat liquid. Highly flammable. Incompatible with strong oxidizing agents, acids, bases, anhydrous metal halides, amino, hydroxyl and carboxyl-containing compounds. Inorganic acids and charcoal may lead to polymerization. Heat, light and moisture sensitive. |
InChIKey | RBACIKXCRWGCBB-UHFFFAOYSA-N |
LogP | 0.68 at 25℃ |
CAS DataBase Reference | 106-88-7(CAS DataBase Reference) |
IARC | 2B (Vol. 47, 71) 1999 |
EPA Substance Registry System | 1,2-Butylene oxide (106-88-7) |
Description and Uses
Butylene oxide is a watery white liquid withan etherial odor. Molecular weight = 72.1 (1,2- and 2,3-isomers);Specific gravity (H2O:1) = 0.83; Boilingpoint = 63.3℃; Freezing/Melting point = - 130℃; Vaporpressure = 142 mmHg at 20℃; 176 mmHg at 25℃;Relative vapor density (air = 1) = 2.2; Relative density ofthe vapor/air mixture at 20C (air = 1) = 1.3; Flashpoint = - 22℃; Autoignition temperature = 439℃.Explosive limits in air: LEL: 1.7%; UEL: 19%. HazardIdentification (based on NFPA-704 M Rating System):Health 2, Flammability 3, Reactivity 2. Soluble in water;solubility = 9.5% at 25℃.
Primarily used as a stabilizer for chlorinated hydrocarbon solvents; also used as a chemical intermediate in the production of butylene glycols
Safety
Symbol(GHS) | GHS02,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H225-H302+H312+H332-H315-H319-H335-H351 |
Precautionary statements | P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P308+P313 |
Hazard Codes | F,Xn |
Risk Statements | 11-20/21/22-36/37/38-40-52/53 |
Safety Statements | 9-16-29-36/37-61-19 |
RIDADR | UN 3022 3/PG 2 |
WGK Germany | 2 |
RTECS | EK3675000 |
Autoignition Temperature | 698 °F |
TSCA | Yes |
HazardClass | 3.1 |
PackingGroup | II |
HS Code | 29109000 |
Hazardous Substances Data | 106-88-7(Hazardous Substances Data) |
Toxicity | LD50 orally in Rabbit: 500 mg/kg LD50 dermal Rabbit 1743 mg/kg |