A1295512
1,1′-Bis(diisopropylphosphino)ferrocene , 98% , 97239-80-0
CAS NO.：97239-80-0
Empirical Formula: C22H36FeP210*
Molecular Weight: 418.31
MDL number: MFCD02684559
EINECS: 677-500-6
| Pack Size | Price | Stock | Quantity |
| 100mg | RMB31.20 | In Stock |
|
| 250MG | RMB35.20 | In Stock |
|
| 1G | RMB84.80 | In Stock |
|
| 5G | RMB367.20 | In Stock |
|
| 25g | RMB1615.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 50-52 °C(lit.) |
| Flash point: | >230 °F |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Powder |
| color | orange-yellow |
| Water Solubility | Insoluble in water. |
| InChI | InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3; |
| InChIKey | LPBBEMRSRONKMN-UHFFFAOYSA-N |
| SMILES | P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23| |
| CAS DataBase Reference | 97239-80-0(CAS DataBase Reference) |
Description and Uses
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P280-P305+P351+P338-P304+P340-P405-P501A |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 37/39-26 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 29319090 |
