1,1'-Bis(diphenylphosphino)ferrocene , 99% , 12150-46-8

Synonym(s):
1,1′-Ferrocenediyl-bis(diphenylphosphine);dppf

CAS NO.：12150-46-8

Empirical Formula: C34H28FeP210*

Molecular Weight: 554.38

MDL number: MFCD00001422

EINECS: 640-119-0

PRODUCT Properties

• Melting point: 181-182 °C (dec.)(lit.)
• storage temp.: 2-8°C
• solubility: Chloroform, Ethyl Acetate
• form: crystal
• color: yellow to orange
• Water Solubility: Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
• Sensitive: Air Sensitive
• Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
• Stability: Stable. Incompatible with strong oxidizing agents.

Description and Uses

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280a-P304+P340-P305+P351+P338-P405-P501a
• Hazard Codes: T,Xi,Xn
• Risk Statements: 25-36/37/38-20/21/22
• Safety Statements: 22-24/25-45-28A-36-26-36/37/39
• RIDADR: 3467
• WGK Germany: 3
• F: 10-23
• TSCA: No
• HazardClass: IRRITANT
• HS Code: 29319090