1,3-Bis(diphenylphosphino)propane , 97% , 6737-42-4

Synonym(s):
dppp

CAS NO.：6737-42-4

Empirical Formula: C27H26P2

Molecular Weight: 412.45

MDL number: MFCD00003050

EINECS: 229-791-2

PRODUCT Properties

• Melting point: 63-65 °C (lit.)
• Boiling point: 529.7±33.0 °C(Predicted)
• Flash point: 235°C
• storage temp.: Inert atmosphere,Room Temperature
• form: Granules or Powder
• color: White to light yellow-beige
• Water Solubility: insoluble
• Sensitive: Air Sensitive
• BRN: 2821785
• InChI: InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
• InChIKey: LVEYOSJUKRVCCF-UHFFFAOYSA-N
• SMILES: P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1

Description and Uses

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-37/39-36
• WGK Germany: 3
• F: 10-23
• TSCA: Yes
• HS Code: 29310095