Phenylboronicacid(containsvaryingamountsofAnhydride) , 99.5% , 98-80-6
Synonym(s):
Benzeneboronic acid;Dihydroxyphenylborane;Phenylboric acid;Phenyl-boric acid;Phenyldihydroxyborane
CAS NO.:98-80-6
Empirical Formula: C6H7BO2
Molecular Weight: 121.93
MDL number: MFCD00002103
EINECS: 202-701-9
Pack Size | Price | Stock | Quantity |
5g | RMB63.20 | In Stock |
|
25g | RMB167.20 | In Stock |
|
250g | RMB895.20 | In Stock |
|
others | Enquire |
PRODUCT Properties
Melting point: | 216-219 °C(lit.) |
Boiling point: | 265.9±23.0 °C(Predicted) |
Density | 1.13±0.1 g/cm3(Predicted) |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) |
form | Crystalline Powder |
pka | 8.83(at 25℃) |
color | White to off-white |
Water Solubility | 10 g/L (20 ºC) |
Sensitive | Hygroscopic |
Merck | 14,1068 |
BRN | 970972 |
Stability: | Hygroscopic |
InChIKey | HXITXNWTGFUOAU-UHFFFAOYSA-N |
Description and Uses
Phenylboronic acid and its derivatives form complexes with polyol compounds such as saccharides and poly(vinyl alcohol) (PVA). Glucose-sensitive hydrogels can be prepared by using phenylhoronic acid as a ligand for target glucose. For example. a copolymer with phenylboronic acid moieties was synthesized by copolymerization of 4V-vinyl-2-pyrrolidone (NVP) and 3-(acryl- amide)phcnylhoronic acid (PBA). The complexes between the NVP-PBA copolymer and PVA enable us to construct glucose-sensitive insulin release systems because the complexes dissociated in response to the glucose concentration.
This phenylboronic acid is soluble in water and the coupling reaction can even be carried out in water. It is compatible with many organic substituents such as esters, ketones, alcohols, etc. which would prohibit the use of Grignard reagents in coupling reactions.
Safety
Symbol(GHS) | GHS07 |
Signal word | Warning |
Hazard statements | H302 |
Precautionary statements | P264-P270-P301+P312-P501 |
Hazard Codes | Xn,Xi,N |
Risk Statements | 22-36/37/38-20/21/22 |
Safety Statements | 22-24/25-36/37/39-26-36 |
WGK Germany | 3 |
RTECS | CY8575000 |
Hazard Note | Harmful |
TSCA | Yes |
HazardClass | IRRITANT, MOISTURE SENSITIVE |
HS Code | 29310095 |
Toxicity | LD50 orl-rat: 740 mg/kg 14KTAK -,693,64 |