Home Categories Organic Chemistry Chloro(1,5-cyclooctadiene)rhodium(I)dimer
A0422656

Chloro(1,5-cyclooctadiene)rhodium(I)dimer , 98% , 12092-47-6

Synonym(s):
Chloro(1,5-cyclooctadiene)rhodium(I) dimer;Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium;1,5-Cyclooctadienerhodium(I) chloride dimer;Bis(1,5-cyclooctadiene)dirhodium(I) dichloride;Di(μ-chloro)bis(1,5-cyclooctadiene)dirhodium(I)

CAS NO.:12092-47-6

Empirical Formula: C16H24Cl2Rh2

Molecular Weight: 493.08

MDL number: MFCD00012415

EINECS: 235-157-6

Pack Size Price Stock Quantity
100mg RMB559.20 In Stock
250mg RMB1255.20 In Stock
1g RMB3999.20 In Stock
others     Enquire
Update time: 2022-07-08

PRODUCT Properties

Melting point: 243 °C (dec.) (lit.)
Density  1.94[at 20℃]
vapor pressure  0Pa at 25℃
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form  Crystals or Crystalline Powder
color  Orange to orange-brown
Water Solubility  1.56g/L at 20℃
Sensitive  Air Sensitive & Hygroscopic
Exposure limits ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Stability: hygroscopic
LogP 3.16 at 20℃

Description and Uses

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
3
TSCA  Yes
HS Code  28439000

RELATED PRODUCTS