A0422656
Chloro(1,5-cyclooctadiene)rhodium(I)dimer , 98% , 12092-47-6
Synonym(s):
Chloro(1,5-cyclooctadiene)rhodium(I) dimer;Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium;1,5-Cyclooctadienerhodium(I) chloride dimer;Bis(1,5-cyclooctadiene)dirhodium(I) dichloride;Di(μ-chloro)bis(1,5-cyclooctadiene)dirhodium(I)
CAS NO.：12092-47-6
Empirical Formula: C16H24Cl2Rh2
Molecular Weight: 493.08
MDL number: MFCD00012415
EINECS: 235-157-6
| Pack Size | Price | Stock | Quantity |
| 100mg | RMB559.20 | In Stock |
|
| 250mg | RMB1255.20 | In Stock |
|
| 1g | RMB3999.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 243 °C (dec.) (lit.) |
| Density | 1.94[at 20℃] |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents. |
| form | Crystals or Crystalline Powder |
| color | Orange to orange-brown |
| Water Solubility | 1.56g/L at 20℃ |
| Sensitive | Air Sensitive & Hygroscopic |
| Exposure limits | ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3 NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| Stability: | hygroscopic |
| LogP | 3.16 at 20℃ |
| NIST Chemistry Reference | Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6) |
| EPA Substance Registry System | Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6) |
Description and Uses
It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.
