Chloro(1,5-cyclooctadiene)iridium(I) dimer , 97% , 12112-67-3

Synonym(s):
[Ir(cod)Cl]2;Bis(1,5-cyclooctadiene)diiridium(I) dichloride;Chloro(1,5-cyclooctadiene)iridium(I) dimer;Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium;[Ir(1,5-cod)Cl]2

CAS NO.：12112-67-3

Empirical Formula: C16H24Cl2Ir2

Molecular Weight: 671.7

MDL number: MFCD00012414

EINECS: 235-170-7

PRODUCT Properties

• Melting point: 205 °C (dec.)(lit.)
• storage temp.: Keep in dark place,Inert atmosphere,2-8°C
• solubility: Chloroform (Slightly), Methanol (Slightly)
• form: Powder
• color: red to orange
• Water Solubility: insoluble
• Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
• InChIKey: XHOSESNLNGITPM-XRGHXPOKSA-L

Description and Uses

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P305+P351+P338-P280a-P304+P340-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• F: 10
• TSCA: No
• HS Code: 28439000