Home Categories Organic Chemistry Chloro(1,5-cyclooctadiene)iridium(I)dimer
A0340656

Chloro(1,5-cyclooctadiene)iridium(I)dimer , 99.95%metalsbasis , 12112-67-3

Synonym(s):
[Ir(cod)Cl]2;Bis(1,5-cyclooctadiene)diiridium(I) dichloride;Chloro(1,5-cyclooctadiene)iridium(I) dimer;Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium;[Ir(1,5-cod)Cl]2

CAS NO.:12112-67-3

Empirical Formula: C16H24Cl2Ir2

Molecular Weight: 671.7

MDL number: MFCD00012414

EINECS: 235-170-7

Pack Size Price Stock Quantity
500mg RMB559.20 In Stock
2g RMB1679.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 205 °C (dec.)(lit.)
storage temp.  Keep in dark place,Inert atmosphere,2-8°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Powder
color  red to orange
Water Solubility  insoluble
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
InChIKey XHOSESNLNGITPM-XRGHXPOKSA-L

Description and Uses

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338-P280a-P304+P340-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
10
TSCA  No
HS Code  28439000

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