B-Methoxy-9-BBN solution , 1.0 Minhexanes , 38050-71-4

Synonym(s):
9-Methoxy-9-borabicyclo[3.3.1]nonane

CAS NO.：38050-71-4

Empirical Formula: C9H17BO

Molecular Weight: 152.04

MDL number: MFCD00074759

EINECS: 253-758-1

PRODUCT Properties

• Boiling point: 57-58 °C(Press: 7 Torr)
• Density: 0.716 g/mL at 25 °C
• Flash point: −9 °F
• InChI: InChI=1S/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3
• InChIKey: UNGDGQYONLTNJZ-UHFFFAOYSA-N
• SMILES: C12B(OC)C(CCC1)CCC2

Description and Uses

Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives. Catalyst for preparation of linear allenes from other allenes 2 Reactant for: Stereoconvergent Suzuki cross-coupling reactions 3 B-alkyl Suzuki-Miyaura cross-coupling reactions 4 Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma 5 Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement.

Safety

• Symbol(GHS): GHS02,GHS07,GHS08,GHS09
• Signal word: Danger
• Hazard statements: H225-H304-H315-H336-H361f-H373-H411
• Precautionary statements: P210-P261-P273-P281-P301+P310-P331
• Hazard Codes: F,Xn,N
• Risk Statements: 11-20/21/22-67-65-62-51/53-48/20-38
• Safety Statements: 16-23-36/37/39-45-62-61-36/37
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 3