(+)-Chloromethyl menthyl ether , 97% , 103128-76-3

CAS NO.：103128-76-3

Empirical Formula: C11H21ClO

Molecular Weight: 204.74

MDL number: MFCD00216950

PRODUCT Properties

• Boiling point: 72 °C/0.4 mmHg (lit.)
• Density: 0.994 g/mL at 25 °C (lit.)
• refractive index: n20/D 1.467(lit.)
• Flash point: 225 °F
• storage temp.: -20°C
• optical activity: [α]24/D +181.0°, c = 2 in methylene chloride

Description and Uses

(+)-Chloromethyl menthyl ether can be used:

• As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
• As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
• To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;⁵- C₂H₅)(PPh₃)COCH₃].

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3