Home Categories Chemical Reagents (+)-Chloromethyl menthyl ether
S0397716

(+)-Chloromethyl menthyl ether , 97% , 103128-76-3

CAS NO.:103128-76-3

Empirical Formula: C11H21ClO

Molecular Weight: 204.74

MDL number: MFCD00216950

Pack Size Price Stock Quantity
5g RMB803.47 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 72 °C/0.4 mmHg (lit.)
Density  0.994 g/mL at 25 °C (lit.)
refractive index  n20/D 1.467(lit.)
Flash point: 225 °F
storage temp.  -20°C
optical activity [α]24/D +181.0°, c = 2 in methylene chloride
CAS DataBase Reference 103128-76-3

Description and Uses

(+)-Chloromethyl menthyl ether can be used:

  • As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
  • As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
  • To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;5- C2H5)(PPh3)COCH3].

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3

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