Home Categories (1S,2S)-1,2-di(naphthalen-1-yl)ethane-1,2-diol
LN8077158

(1S,2S)-1,2-di(naphthalen-1-yl)ethane-1,2-diol , 229184-99-0

CAS NO.:229184-99-0

Empirical Formula: C22H18O2

Molecular Weight: 314.38

MDL number: MFCD01863520

Pack Size Price Stock Quantity
1g RMB2962.40 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 149-151 °C (lit.)
optical activity [α]23/D 25°, c = 1 in chloroform

Description and Uses

(S, S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol can be used as:

  • A ligand in the asymmetric sulfoxidation of dihydrothienopyrimidine.
  • A reactant for the preparation of (2S,2′S)-[(1S,2S)-1,2-bis(naphthalen-1-yl)ethane-1,2-diyl] bis[2-(dimethylamino)propanoate], a chiral bisester ligand via condensation reaction with N,N-dimethylamino acid using aldol-Tishchenko condensation catalyst.
  • A reactant to synthesize diol-SnCl4 chiral Bronsted acid complex, which is employed as a catalyst in the allylboration of aldehydes.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3

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