PRODUCT Properties
Melting point: | 27°C (estimate) |
Boiling point: | 135-136 °C (lit.) |
Density | 0.8 g/mL at 25 °C (lit.) |
refractive index | n |
Flash point: | 74 °F |
storage temp. | 2-8°C |
solubility | Not miscible or difficult to mix. |
form | Liquid |
color | Clear colorless to faintly yellow |
Specific Gravity | 0.817 |
BRN | 1697275 |
CAS DataBase Reference | 871-84-1(CAS DataBase Reference) |
EPA Substance Registry System | 1,7-Octadiyne (871-84-1) |
Description and Uses
1,7-Octadiyne is an useful bifunctional chain extension unit. It participates in the formation of uranium(IV) vinyl complexes. It reacts with frustrated Lewis pair P(o-tolyl)3/B(C6F5)3 by acetylene C-C coupling to yield the zwitterionic product. It undergoes the reductive cyclization during reaction with Re2Cl4(?-dppm)2 (dppm = Ph2PCH2PPh2) and affords quadruply bonded dirhenium(III) complex Re2Cl3(?,η2-C8H7)(?-dppm)2.
Safety
Symbol(GHS) | GHS02,GHS07 |
Signal word | Warning |
Hazard statements | H226-H315-H319-H335 |
Precautionary statements | P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 |
Hazard Codes | Xi |
Risk Statements | 10-36/37/38 |
Safety Statements | 16-26-36/37/39 |
RIDADR | UN 3295 3/PG 3 |
WGK Germany | 3 |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | III |
HS Code | 29012990 |