(Methylcyclopentadienyl)manganese(I)tricarbonyl , 96% , 12108-13-3
Synonym(s):
(Methylcyclopentadienyl)tricarbonylmanganese;Ethyl MMT;MCMT;MMT;Tricarbonyl(2-methylcyclopentadienyl)manganese
CAS NO.：12108-13-3
Empirical Formula: C9H7MnO35*
Molecular Weight: 218.09
MDL number: MFCD00001426
EINECS: 235-166-5
| Pack Size | Price | Stock | Quantity |
| 5g | RMB24.00 | In Stock |
|
| 25g | RMB68.00 | In Stock |
|
| 100g | RMB217.60 | In Stock |
|
| others | Enquire |
PRODUCT Properties
| Melting point: | -1 °C (lit.) |
| Boiling point: | 232-233 °C (lit.) |
| Density | 1.38 g/mL at 25 °C (lit.) |
| vapor density | >1 (vs air) |
| vapor pressure | 0.05 mm Hg ( 20 °C) |
| refractive index | n |
| Flash point: | 205 °F |
| storage temp. | Poison room |
| form | liquid |
| color | yellow |
| Specific Gravity | 1.388 |
| Water Solubility | Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone |
| Sensitive | Air Sensitive |
| Merck | 14,6223 |
| Exposure limits | ACGIH: TWA 0.2 mg/m3 (Skin) OSHA: Ceiling 5 mg/m3 NIOSH: IDLH 500 mg/m3; TWA 0.2 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3 |
| Stability: | Stable. Incompatible with strong oxidizing agents. |
| InChIKey | LYHJNAIHGFWRKM-UHFFFAOYSA-N |
| LogP | 3.4 at 26℃ |
| CAS DataBase Reference | 12108-13-3(CAS DataBase Reference) |
| EPA Substance Registry System | Methylcyclopentadienyl manganese tricarbonyl (12108-13-3) |
Description and Uses
Manganese, tricarbonyl methylcyclopentadienyl is a dark orange liquid. Faintly pleasant, herb-like odor. Molecular weight= 218.10;Boiling point=232℃; Freezing/Melting point=18℃; Flash point=74℃; 96℃. Hazard Identification (based on NFPA-704 M Rating System): Health 3, Flammability 0, Reactivity 0. Practically insoluble in water.
Methylcyclopentadienyl manganese tricarbonyl is used for doping of ZnSe nanocrystals
It can also be used as a reactant for:
Aldol addition reactions
Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Molecular fragmentation using shaped femtosecond laser pulses
Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE)
Safety
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H301-H310+H330-H315-H372-H410 |
| Precautionary statements | P262-P273-P280-P301+P310+P330-P302+P352+P310-P304+P340+P310 |
| Hazard Codes | T,N,T+ |
| Risk Statements | 23/24/25-40-50/53-48/23-38-26-24/25 |
| Safety Statements | 23-26-36/37/39-45-61-60-36/37-28 |
| RIDADR | UN 3281 6.1/PG 2 |
| OEB | C |
| OEL | TWA: 0.2 mg/m3 [skin] |
| WGK Germany | 3 |
| RTECS | OP1450000 |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| Hazardous Substances Data | 12108-13-3(Hazardous Substances Data) |
| Toxicity | LD50 orally in mice, guinea pig, rabbit: 352; 905; 95 mg/kg; orally in male, female rats: 175 ±33; 89 ±14; LC50 inhalation in rat: 0.22 mg/l (Stara) |
