Zirconium(IV) chloride , ≥99.9%metalsbasis , 10026-11-6

Synonym(s):
Tetrachlorozirconium;Zirconium tetrachloride;Zirconium(IV) chloride

CAS NO.：10026-11-6

Empirical Formula: Cl4Zr

Molecular Weight: 233.04

MDL number: MFCD00011306

EINECS: 233-058-2

PRODUCT Properties

• Melting point: 437 °C
• Boiling point: 331°C
• Density: 2.8 g/mL at 25 °C(lit.)
• vapor pressure: 1 mm Hg ( 190 °C)
• storage temp.: Store below +30°C.
• solubility: Soluble in alcohol, ether, hydrochloric acid.
• form: powder
• color: White
• Specific Gravity: 2.803
• PH: <1 (H2O, 20℃)(saturated aqueous solution)
• Water Solubility: Reacts with water.
• Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
• Sensitive: Moisture Sensitive & Hygroscopic
• Merck: 14,10174
• crystal system: Monoclinic
• Space group: P2/c
• Lattice constant:
  • a/nm: 0.636
  • b/nm: 0.741
  • c/nm: 0.626
  • α/o: 90
  • β/o: 109.3
  • γ/o: 90
  • V/nm3: 0.2782
• Exposure limits: ACGIH: TWA 5 mg/m3; STEL 10 mg/m3; NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3

Description and Uses

Zirconium tetrachloride is commonly utilized as a Lewis acid catalyst in many organic synthesis reactions. It is an important source for organometallic complexes of zirconium. It is practiced in many areas like nuclear industry, metal industry, photography, glass, and ceramic industry.

Safety

• Symbol(GHS): GHS05
• Signal word: Danger
• Hazard statements: H290-H314
• Precautionary statements: P234-P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338
• Hazard Codes: C
• Risk Statements: 14-22-34-35
• Safety Statements: 26-36/37/39-45-8
• RIDADR: UN 2503 8/PG 3
• WGK Germany: 3
• RTECS: ZH7175000
• F: 19
• TSCA: Yes
• HS Code: 2827 39 85
• HazardClass: 8
• PackingGroup: III
• Toxicity: LD50 in mice, rats (mg/kg): 665, 1688 orally (Zhilova, Kasparov)