Home Categories Organic Chemistry Trimethyltin chloride
A7744612

Trimethyltin chloride , Analysis standard , 1066-45-1

Synonym(s):
Chlorotrimethylstannane

CAS NO.:1066-45-1

Empirical Formula: C3H9ClSn

Molecular Weight: 199.27

MDL number: MFCD00000520

EINECS: 213-917-8

Pack Size Price Stock Quantity
250MG RMB287.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 37-39 °C (lit.)
Boiling point: 148 °C
Density  0.988 g/mL at 25 °C
Flash point: 207 °F
storage temp.  Poison room
solubility  Chloroform (Slightly)
form  Liquid
Specific Gravity 1.356
color  White
Odor Strong unpleasant stench; no threshold data available
Water Solubility  Soluble in water, chloroform and organic solvents.
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN  3535111
Exposure limits ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability: Moisture Sensitive
InChIKey KWTSZCJMWHGPOS-UHFFFAOYSA-M
CAS DataBase Reference 1066-45-1(CAS DataBase Reference)
EPA Substance Registry System Trimethyltin chloride (1066-45-1)

Description and Uses

Trimethyltin chloride is an organotin reagent widely used in transferring trimethylstannyl groups onto the substrates to synthesize various organostannanes. Trimethylstannyl compounds derived from this reagent, are extensively used in the palladium-catalyzed Stille coupling reactions.

Safety

Symbol(GHS) 
GHS06,GHS09
Signal word  Danger
Hazard statements  H300+H310+H330-H410
Precautionary statements  P262-P273-P280-P301+P310+P330-P302+P352+P310-P304+P340+P310
Hazard Codes  T+,N,F
Risk Statements  26/27/28-50/53-51/53-36/37-19-11-34-40-65-62-48/23/25-36/37/38
Safety Statements  28-36/37-45-61-27-26-16-60-62
RIDADR  UN 3146 6.1/PG 2
WGK Germany  3
RTECS  WH6850000
10-21
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29319090
Hazardous Substances Data 1066-45-1(Hazardous Substances Data)
Toxicity LD50 oral (rat) 12.6 mg/kg
PEL (OSHA) 0.1 mg tin/m3
The ACGIH has established the following uniform exposure limits for all organotin compounds based on the concentration of tin in air:
TLV-TWA (ACGIH) 0.1 mg tin/m3
STEL (ACGIH) 0.2 mg tin/m3

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