Home Categories Organic Chemistry Tris(triphenylphosphine)ruthenium(II) dichloride
A7732012

Tris(triphenylphosphine)ruthenium(II) dichloride , 98% , 15529-49-4

CAS NO.:15529-49-4

Empirical Formula: C54H45Cl2P3Ru

Molecular Weight: 958.83

MDL number: MFCD00013077

EINECS: 239-569-7

Pack Size Price Stock Quantity
1G RMB222.40 In Stock
5G RMB719.20 In Stock
25G RMB2399.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 159 °C
storage temp.  Inert atmosphere,Room Temperature
solubility  Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
form  Solution
color  Clear
Water Solubility  insoluble
Sensitive  Air & Moisture Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
BRN  4935939
InChI InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChIKey QUVLSIIMVTXAPD-UHFFFAOYSA-M
SMILES P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl

Description and Uses

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P501
Hazard Codes  Xn
Risk Statements  20/21/22-20/21
Safety Statements  36/37-22
RIDADR  2811
WGK Germany  3
TSCA  No
HS Code  28439000

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