Home Categories Organic Chemistry TEMPO
A7692712

TEMPO , 98% , 2564-83-2

Synonym(s):
2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical;2,2,6,6-Tetramethylpiperidine 1-oxyl;2,2,6,6-Tetramethylpiperidine-1-oxyl (free radical);Tempo

CAS NO.:2564-83-2

Empirical Formula: C9H18NO*

Molecular Weight: 156.25

MDL number: MFCD00009599

EINECS: 219-888-8

Pack Size Price Stock Quantity
1G RMB23.20 In Stock
5G RMB35.20 In Stock
25G RMB48.00 In Stock
100G RMB164.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 36-38 °C(lit.)
Boiling point: 193°C
Density  1 g/cm3
vapor pressure  0.4 hPa (20 °C)
refractive index  1.4350 (estimate)
Flash point: 154 °F
storage temp.  Store below +30°C.
solubility  9.7g/l
form  Powder
color  Yellow to green
PH 8.3 (9g/l, H2O, 20℃)
Water Solubility  Soluble in all organic solvents. Insoluble in water.
Merck  14,9140
BRN  1422418
Stability: Stable. Incompatible with strong acids, strong oxidizing agents. Refrigerate.
InChIKey RVWUHFFPEOKYLB-UHFFFAOYSA-N

Description and Uses

2,2,6,6-Tetramethylpiperidine is a product that is used for the most diverse purposes because of its strong basicity, for example, as a light stabilizer for polyolefins, as a cocatalyst in olefin polymerizations (Ziegler catalysts), as a building block for the synthesis of pharmaceuticals and crop protection products, as a cocatalyst in the synthesis of dichloroacetyl chloride. The 4-unsubstituted 2.2.6,6-tetramethylpiperidine is generally prepared from the corresponding 4-oxo compound. It is known that triacetonamine can be converted by hydrazine to the hydrazone, which is then cleaved in the presence of alkali into 2,26,6-tetramethylpiperidine and nitrogen.

TEMPO(2,2,6,6-Tetramethylpiperidinooxy) is a stable radical prepared through the oxidation of 2,2,6,6-tetramethylpiperidine. TEMPO has a wide range of applications including use as a free radical scavenger, a reagent in organic synthe sis and as a structural probe in electron spin resonance spectroscopy. TEMPO can also be used as a mediator in free radical polymerization.

Safety

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314-H412
Precautionary statements  P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,Xi
Risk Statements  34-36/37/38
Safety Statements  26-36/37/39-45-24/25
RIDADR  UN 3263 8/PG 2
WGK Germany  3
RTECS  TN8991900
Autoignition Temperature 275 °C
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29333999

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