A7683358
α-Methylene-γ-butyrolactone , 10mMinDMSO , 547-65-9
Synonym(s):
α′-Angelicalactone;3-Methylenedihydro-2(3H)-furanone;5-Methylenedihydro-2(3H)-furanone;alpha-Methylene-gamma-butyrolactone;Tulipane
CAS NO.：547-65-9
Empirical Formula: C5H6O2
Molecular Weight: 98.1
MDL number: MFCD00005407
EINECS: 208-931-6
| Pack Size | Price | Stock | Quantity |
| 1ml | RMB159.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | <25 °C |
| Boiling point: | 86-88 °C12 mm Hg(lit.) |
| Density | 1.119 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 99 °F |
| storage temp. | 2-8°C |
| solubility | water: soluble(lit.) |
| form | Liquid |
| color | Clear colorless to light yellow or slightly pink |
| Merck | 14,6062 |
| BRN | 107939 |
| InChIKey | GSLDEZOOOSBFGP-UHFFFAOYSA-N |
| CAS DataBase Reference | 547-65-9(CAS DataBase Reference) |
| NIST Chemistry Reference | «alpha»-Methylene-«gamma»-butyrolactone(547-65-9) |
| EPA Substance Registry System | 2(3H)-Furanone, dihydro-3-methylene- ( (547-65-9) |
Description and Uses
Tulipalin A is an unsubstituted -methylene-butyrolaetone eontained in the sap of tulips, Alstroemeria spp. (Peruvian lily) and Erythronium (dog tooth violet, fawn-lily). Tulipalin B seems to have a weak capacities to sensitize.
α-Methylene-γ-butyrolactone (Tulipane) was used to develop optically active spiro-[butyrolactone-pyrrolidine] via Cu(I)-catalyzed exo-selective 1,3-dipolar cycloaddition of azomethine ylides.
Safety
| Symbol(GHS) |   GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | H226-H317-H412 |
| Precautionary statements | P210-P233-P240-P273-P280-P303+P361+P353 |
| Hazard Codes | Xn |
| Risk Statements | 42/43-52/53-10 |
| Safety Statements | 23-36/37-61-45 |
| RIDADR | 1993 |
| WGK Germany | 3 |
| RTECS | LU3580400 |
| F | 1-8-10 |
| HazardClass | 3.2 |
| PackingGroup | III |
| HS Code | 29349990 |
