Home Categories Organic Chemistry Sodium thiophenolate
A7540312

Sodium thiophenolate , 90% , 930-69-8

Synonym(s):
Benzenethiol sodium salt;Sodium thiophenoxide;Thiophenol sodium salt

CAS NO.:930-69-8

Empirical Formula: C6H7NaS

Molecular Weight: 134.17

MDL number: MFCD00066460

EINECS: 213-224-0

Update time: 2022-07-08

PRODUCT Properties

Melting point: >300 °C (lit.)
solubility  DMSO (Slightly), Methanol (Slightly, Sonicated)
form  Powder
color  Off-white to yellow to beige
Hydrolytic Sensitivity 0: forms stable aqueous solutions
BRN  3597302
Stability: Hygroscopic

Description and Uses

Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:

  • As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
  • Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
  • Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
  • Synthesis of Et4N+ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)6]2-.

Safety

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 1759 8/PG 3
WGK Germany  3
1-10-13
TSCA  No
HazardClass  6.1(b)
PackingGroup  III
HS Code  29309090

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