Home Categories Organic Chemistry Sodium trifluoromethanesulfonate
A7265212

Sodium trifluoromethanesulfonate , 98% , 2926-30-9

Synonym(s):
Sodium triflate;Trifluoromethanesulfonic acid sodium salt

CAS NO.:2926-30-9

Empirical Formula: CF3NaO3S

Molecular Weight: 172.06

MDL number: MFCD00061607

Pack Size Price Stock Quantity
5G RMB39.20 In Stock
25G RMB126.40 In Stock
100G RMB479.20 In Stock
500g RMB1835.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 253-255 °C (lit.)
storage temp.  Inert atmosphere,Room Temperature
form  Powder
color  White to off-white
Water Solubility  soluble
Sensitive  Hygroscopic
Hydrolytic Sensitivity 0: forms stable aqueous solutions
BRN  3728797
InChIKey KKVTYAVXTDIPAP-UHFFFAOYSA-M
CAS DataBase Reference 2926-30-9(CAS DataBase Reference)

Description and Uses

Sodium trifluoromethanesulfonate is commonly known as trifluoromethanesulfonic acid or TFMS. Possessing unique properties, TFMS is water-soluble, anionic, and boasts a range of valuable attributes. As a colorless, odorless, and non-toxic substance, TFMS finds widespread use as a reagent in organic synthesis, a catalyst in industrial applications, and a buffer in various biochemical experiments. In scientific research, TFMS stands out due to its robust acidity, enabling it to act as a potent catalyst in organic synthesis. Additionally, it effectively serves as a reliable buffer at pH levels, ensuring precise pH maintenance in biochemical experiments. As an anionic compound, TFMS functions as a strong acid in solution, facilitating the donation of protons to other molecules, thus reducing the pH.

Sodium trifluoromethanesulfonate can be employed as a reagent for the preparation of:

  • Aryl fluorides via silver-catalyzed fluorination of arylstannanes.
  • Ionic liquids such as N, N -dialkylpyrrolidinium triflate, N,N-dialkylimidazolium triflate, and N-alkylpyridinium triflate.

It can be also used as supporting electrolyte in electrochemical O-glycosylation of primary alcohols with O-protected thioglycosides.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,C,Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  26-37/39
WGK Germany  3
3-10
Hazard Note  Corrosive
TSCA  No
HS Code  29049090

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