Home Categories Organic Chemistry Nitromethane
A6172112

Nitromethane , Analysis of standard products,> 99.5%(GC) , 75-52-5

Synonym(s):
Mononitromethane, Nitrocarbol;Nitromethane;Nitromethane in dimethyl sulfoxide;Nitromethane solution

CAS NO.:75-52-5

Empirical Formula: CH3NO2

Molecular Weight: 61.04

MDL number: MFCD00007400

EINECS: 200-876-6

Update time: 2022-07-08

PRODUCT Properties

Melting point: ?29 °C (lit.)
Boiling point: 101.2 °C (lit.)
Density  1.127 g/mL at 25 °C (lit.)
vapor density  2.1 (vs air)
vapor pressure  27.3 mm Hg ( 20 °C)
refractive index  n20/D 1.382(lit.)
Flash point: 95 °F
storage temp.  Flammables area
solubility  105g/l
pka 10.2(at 25℃)
form  Liquid
color  APHA: ≤10
Relative polarity 6.8
Odor Disagreeable fruity odor
PH Range 6.4 at 0.01 g/l at 20 °C
PH 6.4 (0.6g/l, H2O, 20℃)
explosive limit 7.3-63.0%(V)
Water Solubility  9.5 g/100 mL (20 ºC)
λmax λ: 380 nm Amax: 1.00
λ: 386 nm Amax: 0.50
λ: 395 nm Amax: 0.20
λ: 400 nm Amax: 0.10
λ: 405 nm Amax: 0.05
λ: 430-700 nm Amax: 0.01
Merck  14,6611
BRN  1698205
Henry's Law Constant 2.24 at 20.00 °C, 3.61 at 30.00 °C, 5.40 at 40.00 °C, 7.97 at 50.00 °C (inert gas stripping, Bene? and Dohnal, 1999)
Exposure limits NIOSH REL: IDLH 750 ppm; OSHA PEL: TWA 100 ppm (250 mg/m3); ACGIH TLV: TWA 20 ppm (adopted).
Dielectric constant 22.7(Ambient)
InChIKey LYGJENNIWJXYER-UHFFFAOYSA-N

Description and Uses

Nitromethane (75-52-5) is an explosive material that was originally manufactured for various applications including mining, construction, demolition, law enforcement, and military uses. However, due to threats of terrorism and increased attention to accident prevention, regulations concerning the transportation, storage, use, and transfer relating to explosives have steadily increased over the last few years and manufacturing limited.

Solvent; chemical synthesis; fuel for professional and model racing cars; in explosive mixtures

Safety

Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Warning
Hazard statements  H226-H302+H332-H351-H361fd
Precautionary statements  P201-P202-P210-P301+P312-P304+P340+P312-P308+P313
Hazard Codes  Xn,F,Xi
Risk Statements  5-10-22
Safety Statements  41
RIDADR  UN 1261 3/PG 2
WGK Germany  2
RTECS  PA9800000
3-10
Autoignition Temperature 784 °F
Hazard Note  Irritant/Flammable
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29042090
Toxicity LC (in air) in guinea pigs: 1000 ppm; LD50 orally in mice: 1.44 g/kg (Weatherby)
IDLA 750 ppm

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