Home Categories Organic Chemistry [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
A6148712

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride , 98% , 15629-92-2

Synonym(s):
(1,3-dppp)NiCl2;1,3-Bis(diphenylphosphino)propane nickel(II) chloride;Ni(dppp)Cl2

CAS NO.:15629-92-2

Empirical Formula: C27H26Cl2NiP2

Molecular Weight: 542.04

MDL number: MFCD00015318

EINECS: 605-052-3

Pack Size Price Stock Quantity
5G RMB31.20 In Stock
25G RMB92.00 In Stock
100G RMB292.00 In Stock
500g RMB1280.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 213 °C (dec.)(lit.)
storage temp.  Inert atmosphere,Room Temperature
form  crystal
color  red
Water Solubility  insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
Exposure limits NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChIKey ZBQUMMFUJLOTQC-UHFFFAOYSA-L
CAS DataBase Reference 15629-92-2(CAS DataBase Reference)

Description and Uses

suzuki reaction.
Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

Safety

Symbol(GHS) 
GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H317-H319-H334-H335-H350
Precautionary statements  P201-P280-P302+P352-P305+P351+P338-P308+P313
Hazard Codes  T,Xn
Risk Statements  49-36/37/38-42/43-40
Safety Statements  53-26-36/37/39-45-24-22
RIDADR  3282
WGK Germany  3
10-21
TSCA  No
HS Code  29319090

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