A6148712
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride , 98% , 15629-92-2
Synonym(s):
(1,3-dppp)NiCl2;1,3-Bis(diphenylphosphino)propane nickel(II) chloride;Ni(dppp)Cl2
CAS NO.:15629-92-2
Empirical Formula: C27H26Cl2NiP2
Molecular Weight: 542.04
MDL number: MFCD00015318
EINECS: 605-052-3
Pack Size | Price | Stock | Quantity |
5G | RMB31.20 | In Stock |
|
25G | RMB92.00 | In Stock |
|
100G | RMB292.00 | In Stock |
|
500g | RMB1280.00 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 213 °C (dec.)(lit.) |
storage temp. | Inert atmosphere,Room Temperature |
form | crystal |
color | red |
Water Solubility | insoluble |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
InChIKey | ZBQUMMFUJLOTQC-UHFFFAOYSA-L |
CAS DataBase Reference | 15629-92-2(CAS DataBase Reference) |
Description and Uses
suzuki reaction.
Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.
Safety
Symbol(GHS) | GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H315-H317-H319-H334-H335-H350 |
Precautionary statements | P201-P280-P302+P352-P305+P351+P338-P308+P313 |
Hazard Codes | T,Xn |
Risk Statements | 49-36/37/38-42/43-40 |
Safety Statements | 53-26-36/37/39-45-24-22 |
RIDADR | 3282 |
WGK Germany | 3 |
F | 10-21 |
TSCA | No |
HS Code | 29319090 |