A5538912
Methyl D-(+)-Lactate , ≥98.0%(GC) , 17392-83-5
Synonym(s):
D -Lactic acid methyl ester;Methyl (R)-(+)-lactate
CAS NO.：17392-83-5
Empirical Formula: C4H8O3
Molecular Weight: 104.1
MDL number: MFCD00004517
EINECS: 241-420-6
| Pack Size | Price | Stock | Quantity |
| 5G | RMB23.20 | In Stock |
|
| 25G | RMB31.20 | In Stock |
|
| 100G | RMB51.20 | In Stock |
|
| 500G | RMB158.40 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| alpha | 8.5 º (c=neat) |
| Boiling point: | 144-145 °C(lit.) |
| Density | 1.09 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 121 °F |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly) |
| form | Liquid |
| pka | 13.07±0.20(Predicted) |
| color | Clear colorless |
| optical activity | [α]21/D +8.4°, neat |
| Water Solubility | miscible, hydrolyses |
| Merck | 14,6094 |
| InChIKey | LPEKGGXMPWTOCB-GSVOUGTGSA-N |
| LogP | -0.719 (est) |
| CAS DataBase Reference | 17392-83-5(CAS DataBase Reference) |
Description and Uses
(+)-Methyl D-lactate can be used as a starting material in the asymmetric preparation of:
- Neomethymycin, a macrolide which contains 12-membered macrolactone that is used as a potent biological agent.
- PM-toxin A.
It can also be used as a chiral pool along with D-(-)-tartaric acid in the stereoselective total synthesis of separacenes A and B via Trost-Rychnovsky alkyne rearrangement, Horner-Wadsworth-Emmons olefination as well as Corey-Bakshi-Shibata reaction.
Safety
| Symbol(GHS) |   GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | H226-H319-H335 |
| Precautionary statements | P210-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37 |
| Safety Statements | 16-24-24/25 |
| RIDADR | UN 3272 3/PG 3 |
| WGK Germany | 1 |
| HazardClass | 3 |
| PackingGroup | III |
| HS Code | 29181100 |
