Home Categories (-)-Methyl (S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate
A5457612

(-)-Methyl (S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate , 95% , 60456-21-5

Synonym(s):
α,β-Isopropylidene-L-glyceric acid methyl ester;Methyl α,β-isopropylidene-L-glycerate;Methyl 2,3-O-isopropylidene-L-glycerate

CAS NO.:60456-21-5

Empirical Formula: C7H12O4

Molecular Weight: 160.17

MDL number: MFCD00066526

Pack Size Price Stock Quantity
1g RMB180.00 In Stock
5G RMB544.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 84-86 °C/15 mmHg (lit.)
Density  1.106 g/mL at 25 °C (lit.)
refractive index  n20/D 1.425(lit.)
Flash point: 78°C
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
form  liquid
color  Pale yellow
optical activity [α]20/D 8.5°, c = 1.5 in acetone
BRN  4292352
InChIKey DOWWCCDWPKGNGX-YFKPBYRVSA-N

Description and Uses

(?)-Methyl (S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate can be used:

  • As a chiral building block to make the key tetrahydrofuran subunit of (?)-gymnodimine, a marine algal toxin.
  • To prepare an enedione by reacting with dimethyl methylphosphonate, BuLi, and phenylglyoxal, which in turn is used to synthesize cyclopentenone derivatives.
  • As a starting material for the preparation of (S)-4,5-dihydroxy-2,3-pentanedione (DPD), a precursor for autoinducer (AI)-2 in bacteria.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Safety Statements  23-24/25
WGK Germany  3
10-23
HS Code  2932990090

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