Home Categories Organic Chemistry (R)-(+)-α-Methyl-1-naphthalenemethylamine
A5451412

(R)-(+)-α-Methyl-1-naphthalenemethylamine , 99% , 3886-70-2

Synonym(s):
(R)-(+)-α-Methyl-1-naphthalenemethylamine

CAS NO.:3886-70-2

Empirical Formula: C12H13N

Molecular Weight: 171.24

MDL number: MFCD00064114

EINECS: 223-425-5

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Update time: 2022-07-08

PRODUCT Properties

Melting point: 135-136 °C
alpha  60 º (c=2, CH3OH)
Boiling point: 153 °C11 mm Hg(lit.)
Density  1.067 g/mL at 20 °C(lit.)
refractive index  n20/D 1.623(lit.)
Flash point: >230 °F
storage temp.  2-8°C
solubility  Chloroform (Slightly), Ethanol (Slightly), Methanol (Slightly)
pka 9.26±0.40(Predicted)
form  Liquid
color  brown
Specific Gravity 1.07
optical activity [α]20/D +55°, c = 2 in ethanol
Water Solubility  Soluble in water (<10/l).
Sensitive  Air Sensitive
BRN  2208025
Stability: Stable. Air-sensitive. Incompatible with acids, oxidizing agents, acid anhydrides, chloroformates, acid chlorides.
InChIKey RTCUCQWIICFPOD-SECBINFHSA-N
CAS DataBase Reference 3886-70-2(CAS DataBase Reference)
EPA Substance Registry System 1-Naphthalenemethanamine, .alpha.-methyl-, (.alpha.R)- (3886-70-2)

Description and Uses

(R)-(+)-1-(1-Naphthyl)ethylamine is a reagent used in the formation of isolated acids via salt formation. It is also a raw material for the synthesis of (R)-1-(1-Naphthyl)ethyl isocyanate. In materials research, the use of Reflectance Absorption Infrared Spectroscopy (RAIRS) can be used to study the structure, bonding and orientation of R-1- nea and (S)-(-)-1-(2-naphthyl)ethylamine (S-2- nea) on Pd(1 1 1).

It is used in chiral synthesis in organic reactions including the synthesis of β-amino acids and the enantioselective of ketones to nitroolefins. Also used as absolute configuration of primary amines determined using chiral (2-nitrophenyl)proline amides and H NMR.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  2735
WGK Germany  3
RTECS  QJ6963000
10-34
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29211990

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