A5408412
2-Methylpyridine , 99% , 109-06-8
Synonym(s):
α-Picoline;2-Methylpyridine;2-Picoline;NSC 3409
CAS NO.:109-06-8
Empirical Formula: C6H7N
Molecular Weight: 93.13
MDL number: MFCD00006332
EINECS: 203-643-7
Update time: 2022-07-08
PRODUCT Properties
Melting point: | -70 °C (lit.) |
Boiling point: | 128-129 °C (lit.) |
Density | 0.942-0.946 at 20 °C
0.943 g/mL at 25 °C (lit.) |
vapor density | 3.2 (vs air) |
vapor pressure | 10 mm Hg ( 24.4 °C) |
refractive index | n |
Flash point: | 79 °F |
storage temp. | Store below +30°C. |
solubility | H2O: freely soluble |
pka | 5.97(at 20℃) |
form | Liquid |
color | Clear pale yellow |
PH | 8.5 (100g/l, H2O, 20℃) |
Odor | Unpleasant |
explosive limit | 1.4-8.6%(V) |
Odor Type | sweaty |
Water Solubility | MISCIBLE |
Sensitive | Hygroscopic |
Merck | 14,7400 |
BRN | 104581 |
Dielectric constant | 9.8000000000000007 |
Stability: | Stable. Flammable. Incompatible with strong oxidizing agents, sulfuric acid, acids, metals, iron (II) sulfate, hydrogen peroxide. Hygroscopic. |
InChIKey | BSKHPKMHTQYZBB-UHFFFAOYSA-N |
LogP | 1.11 at 20℃ |
CAS DataBase Reference | 109-06-8(CAS DataBase Reference) |
NIST Chemistry Reference | Pyridine, 2-methyl-(109-06-8) |
EPA Substance Registry System | 2-Methylpyridine (109-06-8) |
Description and Uses
2-Picoline is used as a reagent in the synthesis of 2-Picolineborane, a non-toxic alternative to sodium borohydride for the labelling of oligosaccharides.
Safety
Symbol(GHS) | GHS02,GHS05,GHS06 |
Signal word | Danger |
Hazard statements | H226-H302+H332-H311-H314-H335 |
Precautionary statements | P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
Hazard Codes | Xn,T |
Risk Statements | 10-20/21/22-36/37-24-20/22 |
Safety Statements | 26-36-45-36/37 |
RIDADR | UN 2313 3/PG 3 |
WGK Germany | 1 |
RTECS | TJ4900000 |
Autoignition Temperature | 995 °F |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | III |
HS Code | 29333999 |
Hazardous Substances Data | 109-06-8(Hazardous Substances Data) |
Toxicity | LD50 orally in rats: 1.41 g/kg (Smyth) |