A5404612
α-Methylene-γ-butyrolactone , 95%, containing ~ 2%2,6-two-uncle butadiecetic tailphenol stabilizer , 547-65-9
Synonym(s):
α′-Angelicalactone;3-Methylenedihydro-2(3H)-furanone;5-Methylenedihydro-2(3H)-furanone;alpha-Methylene-gamma-butyrolactone;Tulipane
CAS NO.:547-65-9
Empirical Formula: C5H6O2
Molecular Weight: 98.1
MDL number: MFCD00005407
EINECS: 208-931-6
Pack Size | Price | Stock | Quantity |
1G | RMB136.00 | In Stock |
|
5G | RMB348.80 | In Stock |
|
25G | RMB1380.00 | In Stock |
|
100G | RMB5000.80 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | <25 °C |
Boiling point: | 86-88 °C12 mm Hg(lit.) |
Density | 1.119 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 99 °F |
storage temp. | 2-8°C |
solubility | water: soluble(lit.) |
form | Liquid |
color | Clear colorless to light yellow or slightly pink |
Merck | 14,6062 |
BRN | 107939 |
InChIKey | GSLDEZOOOSBFGP-UHFFFAOYSA-N |
CAS DataBase Reference | 547-65-9(CAS DataBase Reference) |
NIST Chemistry Reference | «alpha»-Methylene-«gamma»-butyrolactone(547-65-9) |
EPA Substance Registry System | 2(3H)-Furanone, dihydro-3-methylene- ( (547-65-9) |
Description and Uses
Tulipalin A is an unsubstituted -methylene-butyrolaetone eontained in the sap of tulips, Alstroemeria spp. (Peruvian lily) and Erythronium (dog tooth violet, fawn-lily). Tulipalin B seems to have a weak capacities to sensitize.
α-Methylene-γ-butyrolactone (Tulipane) was used to develop optically active spiro-[butyrolactone-pyrrolidine] via Cu(I)-catalyzed exo-selective 1,3-dipolar cycloaddition of azomethine ylides.
Safety
Symbol(GHS) | GHS02,GHS07 |
Signal word | Warning |
Hazard statements | H226-H317-H412 |
Precautionary statements | P210-P233-P240-P273-P280-P303+P361+P353 |
Hazard Codes | Xn |
Risk Statements | 42/43-52/53-10 |
Safety Statements | 23-36/37-61-45 |
RIDADR | 1993 |
WGK Germany | 3 |
RTECS | LU3580400 |
F | 1-8-10 |
HazardClass | 3.2 |
PackingGroup | III |
HS Code | 29349990 |