Home Categories Organic Chemistry Lithium tetrachlorocuprate
A5306712

Lithium tetrachlorocuprate , 0.1MinTHF , 15489-27-7

CAS NO.:15489-27-7

Empirical Formula: Cl4CuLi2

Molecular Weight: 219.24

MDL number: MFCD00011081

EINECS: 203-726-8

Pack Size Price Stock Quantity
100ML RMB271.20 In Stock
500ML RMB1088.00 In Stock
800ml RMB1519.20 In Stock
1l RMB1636.80 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 66°C
Density  0.91 g/mL at 25 °C
Flash point: 1 °F
storage temp.  Flammables area
solubility  Difficult to mix.
form  Liquid
Specific Gravity 0.91
color  Dark orange
Sensitive  Moisture Sensitive
Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Description and Uses

Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines.

Safety

Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H371-H372-H333-H225-H302-H319-H335-H351
Precautionary statements  P201-P303+P361+P353-P501a-P233-P240-P241+P242+P243-P260-P264-P270-P271-P302+P352+P332+P313+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P308+P311-P403+P233-P405-P501-P210-P280-P301+P312+P330-P305+P351+P338-P370+P378-P403+P235
Hazard Codes  F,Xi,Xn
Risk Statements  11-19-36/37-40
Safety Statements  16-29-33-46-37-36-13
RIDADR  UN 1993 3/PG 2
WGK Germany  1
10-21
HazardClass  3
PackingGroup  II
HS Code  28429090

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