Home Categories Chemical Reagents Lanthanum(III) trifluoromethanesulfonate
A5247712

Lanthanum(III) trifluoromethanesulfonate , 98% , 52093-26-2

Synonym(s):
La(OTf)3;Lanthanum tris(trifluoromethanesulfonate);Lanthanum(III) triflate;Trifluoromethanesulfonic acid lanthanum salt;Tris(trifluoromethanesulfonato)lanthanum

CAS NO.:52093-26-2

Empirical Formula: C3F9LaO9S3

Molecular Weight: 586.11

MDL number: MFCD00077560

EINECS: 628-666-3

Pack Size Price Stock Quantity
1G RMB37.60 In Stock
5G RMB96.00 In Stock
25G RMB368.00 In Stock
100G RMB1094.40 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: >300°C
Density  1.7
storage temp.  Inert atmosphere,2-8°C
solubility  Water (Slightly)
form  Crystalline Powder
color  White to light beige
Water Solubility  Soluble in water.
Sensitive  Hygroscopic
Hydrolytic Sensitivity 6: forms irreversible hydrate
BRN  9009103
Stability: hygroscopic
InChI InChI=1S/3CHF3O3S.La/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChIKey WGJJZRVGLPOKQT-UHFFFAOYSA-K
SMILES C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[La+3]
CAS DataBase Reference 52093-26-2(CAS DataBase Reference)

Description and Uses

Lanthanum trifluoromethanesulfonate is a water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes. It is an effective catalyst for the Baylis-Hillman reaction. It also catalyzes Michael additions to methyl vinyl ketone in water.

Safety

Symbol(GHS) 
GHS05,GHS07
Signal word  Warning
Hazard statements  H314-H318-H315-H319-H335
Precautionary statements  P260h-P301+P330+P331-P303+P361+P353-P405-P501a-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  UN 1759 8/PG III
WGK Germany  3
3-10
Hazard Note  Irritant
HazardClass  8
PackingGroup  III
HS Code  28469099

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