Home Categories Chemical Reagents (<i>R</i>,<i>R</i>)-(+)-Hydrobenzoin
A5054412

(<i>R</i>,<i>R</i>)-(+)-Hydrobenzoin , ≥99% , 52340-78-0

Synonym(s):
(R,R)-1,2-Diphenyl-1,2-ethanediol;(R,R)-1,2-Diphenylethylene glycol

CAS NO.:52340-78-0

Empirical Formula: C14H14O2

Molecular Weight: 214.26

MDL number: MFCD00064254

Pack Size Price Stock Quantity
1G RMB114.40 In Stock
5G RMB301.60 In Stock
25G RMB1332.00 In Stock
100g RMB5224.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 146-149 °C(lit.)
Boiling point: 314.4°C (rough estimate)
Density  1.0781 (rough estimate)
refractive index  95 ° (C=1, CHCl3)
storage temp.  Sealed in dry,Room Temperature
solubility  Soluble in DMSO
pka 13.38±0.20(Predicted)
form  Crystalline Powder or Crystals
color  White to beige or light brown
optical activity [α]28/D +93°, c = 2.5 in ethanol
Merck  14,4777
BRN  2050815
CAS DataBase Reference 52340-78-0(CAS DataBase Reference)

Description and Uses

(R,R)-(+)-Hydrobenzoin may be used in the oxyselenenylation step in the multi-step synthesis of cyclopentitols and aminocyclopentitols from cyclopentene. It may also be used as a ligand for the asymmetric addition of diethylzinc to aldehydes in the presence or absence of titanium tetra-isopropoxide to form (R)- or (S)-form of the corresponding secondary alcohol, respectively.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  3
10
HS Code  29062990

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