Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde , 93% , 5453-80-5

Synonym(s):
5-Norbornene-2-carboxaldehyde

CAS NO.：5453-80-5

Empirical Formula: C8H10O

Molecular Weight: 122.16

MDL number: MFCD00167568

EINECS: 226-698-9

PRODUCT Properties

• Boiling point: 67-70 °C12 mm Hg(lit.)
• Density: 1.03 g/mL at 20 °C(lit.)
• refractive index: n20/D 1.490(lit.)
• Flash point: 123 °F
• storage temp.: Flammables area
• form: Powder
• Specific Gravity: 1.032
• color: White to yellow to beige
• Water Solubility: insoluble
• BRN: 1363813
• CAS DataBase Reference: 5453-80-5(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde(5453-80-5)
• EPA Substance Registry System: Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde (5453-80-5)

Description and Uses

5-Norbornene-2-carboxaldehyde was used in transition metal-catalyzed synthesis of norbornene-derived homopolymers having pendent t-Boc-protected quinizarin moieties for patterned fluorescence images. It acts as Diels-Alder adduct of acrolein and cyclopentadiene. It can be used as protected form of acrolein, from which the double bond may be liberated by cycloreversion, e.g. in a useful synthesis of 2-vinylimidazole.

Safety

• Symbol(GHS): GHS02
• Signal word: Warning
• Hazard statements: H226
• Precautionary statements: P210
• Hazard Codes: Xi
• Risk Statements: 10-36/37/38
• Safety Statements: 23-37/39-26-16
• RIDADR: UN 1989 3/PG 3
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 3
• PackingGroup: III
• HS Code: 29122990