Home Categories Chemical Reagents Diethyl (Chloromethyl)phosphonate
A3532612

Diethyl (Chloromethyl)phosphonate , >98.0%(GC) , 3167-63-3

Synonym(s):
Chloromethylphosphonic acid diethyl ester;NSC 67753

CAS NO.:3167-63-3

Empirical Formula: C5H12ClO3P

Molecular Weight: 186.57

MDL number: MFCD00010189

EINECS: 221-632-5

Pack Size Price Stock Quantity
250mg RMB104.00 In Stock
1G RMB208.80 In Stock
5G RMB779.20 In Stock
25g RMB3071.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 109-110 °C10 mm Hg(lit.)
Density  1.2 g/mL at 25 °C(lit.)
refractive index  n20/D 1.437(lit.)
Flash point: 188 °F
storage temp.  2-8°C
form  Liquid
color  Clear colorless to light yellow
Specific Gravity 1.2
BRN  1363361
EPA Substance Registry System Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3)

Description and Uses

Reactant involved in:

  • Subsequent alkylation after nucleophilic substitution
  • One-pot alkylation-boration of α-haloalkylphosphonates
  • Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
  • Phosphorylation leading to P-containing cyclopropanes
  • Wadsworth-Emmons reactions
  • Ring expansion of zircnacycles via carbenoid insertion

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  29319090

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