Home Categories Chemical Reagents 4,4'-Di-<i>tert</i>-butylbiphenyl
A3362612

4,4'-Di-<i>tert</i>-butylbiphenyl , ≥98.0%(GC) , 1625-91-8

CAS NO.:1625-91-8

Empirical Formula: C20H26

Molecular Weight: 266.42

MDL number: MFCD00008834

EINECS: 216-615-4

Pack Size Price Stock Quantity
5G RMB31.20 In Stock
25G RMB119.20 In Stock
100G RMB375.20 In Stock
500g RMB1503.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 126-130 °C(lit.)
Boiling point: 190-192 °C13 mm Hg(lit.)
Density  0.9463 (estimate)
refractive index  1.5928 (estimate)
Flash point: 190-192°C/13mm
storage temp.  Sealed in dry,Room Temperature
solubility  dioxane: 0.1 g/mL, clear
form  Crystalline Powder
color  Light yellow to yellow-orange
BRN  2095855
CAS DataBase Reference 1625-91-8(CAS DataBase Reference)
NIST Chemistry Reference 4,4'-Di-tert-butylbiphenyl(1625-91-8)

Description and Uses

It is used in the generation of 1,2-di(lithiomethyl)benzene. It is found to accept electrons from Li metal to give a radical anion which is highly effective in the conversion of alkyl halides to alkyllithiums. 4,4?-Di-tert-butylbiphenyl is used in production of homoallylic amine derivatives. It is also used in the preparation of lithium di-tert-butylbiphenylide, a radical anion, superior to sodium or lithium naphthalenides for metalation reactions. Along with lithium, 4,4?-Di-tert-butylbiphenyl catalyzes; reaction of chloromethyl ethyl ether and different carbonyl compounds to yield corresponding hydroxyethers and reductive opening of N-phenylazetidine.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H335-H315-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
Safety Statements  22-24/25
WGK Germany  3
HS Code  29029090

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