Home Categories Organic Chemistry 2,7-Dibromofluorene
A3149912

2,7-Dibromofluorene , 98% , 16433-88-8

CAS NO.:16433-88-8

Empirical Formula: C13H8Br2

Molecular Weight: 324.01

MDL number: MFCD00019048

EINECS: 629-430-2

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Update time: 2022-07-08

PRODUCT Properties

Melting point: 164-166 °C (lit.)
Boiling point: 329.77°C (rough estimate)
Density  1.7203 (estimate)
refractive index  1.6000 (estimate)
storage temp.  Sealed in dry,Room Temperature
solubility  Chloroform (Slightly)
form  Crystalline Powder
color  White to off-white
BRN  2049205
InChIKey AVXFJPFSWLMKSG-UHFFFAOYSA-N

Description and Uses

2,7-Dibromofluorene is a halogenated polycyclic aromatic compound and its vapour pressure has been measured using the Knudsen effusion method.

2,7-Dibromofluorene was used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It may be used in the synthesis of conjugated polymer, poly[9,9′-bis(6′′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays. It was used in the preparartion of blue photoluminescent unsymmetrically substituted polyfluorene. It was also used in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9′-position of the fluorene ring, such as:

  • 9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene
  • 9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene
  • 9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
TSCA  T
HazardClass  IRRITANT
HS Code  29420000

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