Cobalt(II)oxide , AR , 1307-96-6

Synonym(s):
Cobaltous oxide

CAS NO.：1307-96-6

Empirical Formula: CoO

Molecular Weight: 74.93

MDL number: MFCD00016031

EINECS: 215-154-6

PRODUCT Properties

• Melting point: 1785 °C
• Density: 6.45
• vapor pressure: 0Pa at 20℃
• solubility: insoluble in H2O; soluble in acid solutions
• form: Powder
• Specific Gravity: 6.45
• color: Green-brown
• Water Solubility: insoluble
• Sensitive: Air Sensitive
• Crystal Structure: NaCl type
• crystal system: Cube
• Merck: 14,2446
• Space group: Fm3m
• Lattice constant:
  • a/nm: 0.4263
  • b/nm: 0.4263
  • c/nm: 0.4263
  • α/o: 90
  • β/o: 90
  • γ/o: 90
  • V/nm3: 0.0775
• Exposure limits: ACGIH: TWA 1 mg/m3; OSHA: TWA 15 mg/m3; TWA 5 mg/m3
• Stability: Stability Stable, but may be moisture sensitive.
• InChI: InChI=1S/Co.O
• InChIKey: IVMYJDGYRUAWML-UHFFFAOYSA-N
• SMILES: O=[Co]
• CAS DataBase Reference: 1307-96-6(CAS DataBase Reference)
• NIST Chemistry Reference: Cobalt monoxide(1307-96-6)
• EPA Substance Registry System: Cobalt(II) oxide (1307-96-6)

Description and Uses

This is obtained as an olive-green powder by heating the metal in air or steam or by thermal decomposition of the hydroxide, carbonate or nitrate. It has the sodium chloride lattice and is antiferromagnetic below 292°K. When heated in oxygen above 400° the black oxide Co3O4 is obtained. This oxide is isomorphous with magnetite Fe3O4, and has tetrahedrally surrounded cobalt(II) ions and octahedrally surrounded cobalt(III) ions. Both these oxides are readily reduced to the metal by heating in hydrogen or with carbon. The reactions of CoO with silica, alumina and zinc oxide are used to form pigments in the ceramic industry.

In pigments for ceramics; glass coloring and decolorization; oxidation catalyst for drying oils, fast-drying paints and varnishes; preparation of cobalt-metal catalysts, Co powder for binder in sintered tungsten carbide; in semiconductors.

Safety

• Symbol(GHS): GHS06,GHS08,GHS09
• Signal word: Danger
• Hazard statements: H301-H317-H330-H334-H350i-H360F-H410
• Precautionary statements: P202-P260-P273-P280-P302+P352-P304+P340+P310
• Hazard Codes: Xn,N,T+
• Risk Statements: 22-43-50/53-42/43-26
• Safety Statements: 24-37-60-61-45-36/37-28
• RIDADR: UN 3288 6.1/PG 3
• WGK Germany: 3
• RTECS: GG2800000
• TSCA: Yes
• HazardClass: 6.1(b)
• PackingGroup: III
• HS Code: 28220000
• Hazardous Substances Data: 1307-96-6(Hazardous Substances Data)
• Toxicity: LD50 orally in rats: 1.70 g/kg (Smyth)