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A1309912

Boc-D-Phg-OH , 98% , 33125-05-2

Synonym(s):
Boc-Phg-OH;Boc-D-Phg-OH;N-α-t.-Boc-D-phenylglycine;N-α-t.-Boc-L-phenylglycine;Boc-D-α-phenylglycine

CAS NO.:33125-05-2

Empirical Formula: C13H17NO4

Molecular Weight: 251.28

MDL number: MFCD00065588

EINECS: 1533716-785-6

Pack Size Price Stock Quantity
1G RMB23.20 In Stock
5G RMB24.00 In Stock
25G RMB73.60 In Stock
100g RMB207.20 In Stock
500G RMB783.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 88-91 °C
alpha  -142 º (c=1% in ethanol)
Boiling point: 407.2±38.0 °C(Predicted)
Density  1.182±0.06 g/cm3(Predicted)
refractive index  -140 ° (C=1, EtOH)
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
solubility  DMSO, Methanol
pka 3.51±0.10(Predicted)
form  Crystalline Powder
color  White
optical activity [α]20/D 141.0±5.0°, c = 1% in ethanol
Water Solubility  Insoluble in water. Slightly soluble in DMSO and methanol.
BRN  3033982
CAS DataBase Reference 33125-05-2(CAS DataBase Reference)

Description and Uses

It is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher's acid ((R)-(+)-?-Methoxy-?-(trifluoromethyl)-phenyl-acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.

Safety

Symbol(GHS) 
GHS07
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362+P364-P403+P233-P501c
Safety Statements  24/25
WGK Germany  3
HazardClass  IRRITANT
HS Code  29242990

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