8-Bromoquinoline , 97% , 16567-18-3

CAS NO.：16567-18-3

Empirical Formula: C9H6BrN

Molecular Weight: 208.05

MDL number: MFCD00191859

EINECS: 630-629-1

PRODUCT Properties

• Melting point: 58-59 °C
• Boiling point: 112-113 °C/0.5 mmHg (lit.)
• Density: 1.594 g/mL at 25 °C (lit.)
• refractive index: n20/D 1.672(lit.)
• Flash point: >230 °F
• storage temp.: Inert atmosphere,2-8°C
• pka: 2.33±0.17(Predicted)
• form: Liquid After Melting
• color: Clear yellow to yellow-brown
• Specific Gravity: 1.594
• Sensitive: Light Sensitive
• InChIKey: PIWNKSHCLTZKSZ-UHFFFAOYSA-N
• CAS DataBase Reference: 16567-18-3(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoline, 8-bromo-(16567-18-3)

Description and Uses

8-Bromoquinoline may be used in the following studies:

• Synthesis of 8-(dimesitylboryl)quinolone (ambiphilic molecule).
• Direct synthesis of 5H-pyrido[3,2,1-ij]quinolin-3-one, via palladium catalyzed coupling reaction with acrolein.
• Preparation of 8-(1-hydroxyethyl)quinolone.
• Preparation of 8-quinolylcyclopentadienyl metal complexes, via reaction with zincated cyclopentadienyl derivatives of Fe, Mn and Re in the presence of bis(triphenylphosphine)palladium(0).
• Synthesis of n,n′-biquinolines by a coupling reaction using tris(triphenylphosphine)nickel(0) and a zerovalent pyridine-nickel complex.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-36-37/39
• WGK Germany: 3
• Hazard Note: Irritant
• HS Code: 29334900